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Ti/nanoTiO2-ZrO2修饰电极电催化氧化葡萄糖
引用本文:方文彦,王凤武SPAN style="FONT-SIZE: .pt,FONT-FAMILY: Times New Roman,serif,mso-bidi-font-size: .pt,mso-bidi-font-family: 宋体,mso-font-kerning: .pt,mso-ansi-language: EN-US,mso-fareast-language: ZH-CN,mso-bidi-language: AR-SA,mso-fareast-font-family: 宋体,mso-hansi-font-family: 宋体">,徐迈,朱传高,魏亦军,朱其永. Ti/nanoTiO2-ZrO2修饰电极电催化氧化葡萄糖[J]. 化工学报, 2010, 61(12): 29-32
作者姓名:方文彦,王凤武SPAN style="  FONT-SIZE: .pt,FONT-FAMILY: Times New Roman,serif,mso-bidi-font-size: .pt,mso-bidi-font-family: 宋体,mso-font-kerning: .pt,mso-ansi-language: EN-US,mso-fareast-language: ZH-CN,mso-bidi-language: AR-SA,mso-fareast-font-family: 宋体,mso-hansi-font-family: 宋体"  >,徐迈,朱传高,魏亦军,朱其永
作者单位:淮南师范学院化学系
摘    要:在无水乙醇和乙酰丙酮混合溶液中,电解Ti金属制得前驱体Ti(OCH2CH34-y)(acac)y,再加入ZrCl4,将上述溶液直接水解、干燥后在450℃煅烧2 h,粉体通过X射线衍射(XRD)分析表明:纳米TiO2-ZrO2粉体呈单分散结构。通过凝胶涂抹、煅烧得到高活性的


Electrocatalytic oxidation of glucose at Ti/nanoTiO2-ZrO2 electrode
FANG Wenyan,WANG Fengwu,XU Mai,ZHU Chuangao,WEI Yijun,ZHU Qiyong. Electrocatalytic oxidation of glucose at Ti/nanoTiO2-ZrO2 electrode[J]. Journal of Chemical Industry and Engineering(China), 2010, 61(12): 29-32
Authors:FANG Wenyan  WANG Fengwu  XU Mai  ZHU Chuangao  WEI Yijun  ZHU Qiyong
Abstract:The precursor Ti(OCH2CH34-y(acac)y was synthesized by electrolysis of titanium and in absolute ethanol and acetyl-acetone solution.0.5 g ZrCl4 was added into the above.Nano-crystalline TiO2-ZrO2 powder was prepared by directs sol-gel method from the precursor and then calcined for 2 h at 400℃. XRD and TEM results showed that the nano-TiO2-ZrO2 of 30—40 nm was obtained.The highly active Ti/nanoTiO2-ZrO2 modified electrode was prepared by using daubing and drying.The results of cyclic voltammetry showed that Ti/nanoTiO2-ZrO2 modified electrode as anode exhibited high electrocatalytic activity for electro-oxidation of glucose.
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