有机酸碱功能化介孔材料的合成与催化应用

综述了近年来有机酸碱功能化介孔材料的合成及其在催化反应中的应用情况。主要从含有有机酸、有机碱及有机酸/碱对等3种类型的有机-无机杂化介孔材料的构筑方式及其催化性能研究等方面进行了概括和总结;探讨了有机酸(碱)的种类及空间分布方式、载体的结构及表面性质等因素对杂化介孔材料催化性能的影响;指出了有机酸碱功能化介孔材料在催化应用中的主要特点和存在的问题,并对今后的发展趋势进行了展望。

Organic-Acid/Base Functionalized Mesoporous Materials: Synthesis and Catalysis

The present review summarizes the recent development in the syntheses and catalytic applications of organic-acid/base functionalized mesoporous materials,including a variety of hybrid materials containing organic acid,organic base or organic acid-base bifunctional groups.The influence of different parameters,such as the type and distribution of organic acid(and/or base),the structure and surface properties of the mesoporous supports,on the catalytic performance of the hybrid materials has been discussed.The main advantages of these hybrid materials,their future development and research trend in the catalysis field have also been pointed out.