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| 臭氧氧化法制备壬二酸单甲酯 | |
| 引用本文： | 艾买提江·萨伍提,吾满江·艾力,司马义·努尔拉.臭氧氧化法制备壬二酸单甲酯[J].精细石油化工,2009,26(3). |
| 作者姓名： | 艾买提江·萨伍提 吾满江·艾力 司马义·努尔拉 |
| 作者单位： | 1. 新疆大学化学化工学院,新疆,乌鲁木齐,830046;中国科学院新疆理化技术研究所,新疆,乌鲁木齐,830011 2. 中国科学院新疆理化技术研究所,新疆,乌鲁木齐,830011 3. 新疆大学化学化工学院,新疆,乌鲁木齐,830046 |
| 基金项目： | 新疆自治区科技厅攻关项目 |
| 摘 要： | 研究了以油酸甲酯为原料,乙酸和正己烷的混合物做溶剂,臭氧氧化法制备壬二酸单甲酯的方法。考察了物料比、臭氧化温度、氧化裂解温度和氧化裂解时间对反应结果的影响。结果表明,合成壬二酸单甲酯的最佳条件为:V(油酸甲酯):V(混合溶剂)=1:4,臭氧化反应温度为10～13℃,氧化裂解温度为90～95℃,氧化裂解时间为2.5 h,反应粗产物用分子蒸馏技术进行分离纯化。在此条件下,壬二酸单甲酯的收率≥78%,纯度≥96%。其结构经过IR,~1H NMR,GC-MS确证。 |
| 关 键 词： | 油酸甲酯 臭氧氧化 壬二酸单甲酯 分子蒸馏 |
SYNTHESIS OF AZELAIC ACID MONOMETHYL ESTER |
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| Amatjan Sawut,Wumanjiang Eli,Ismayil Nurulla.SYNTHESIS OF AZELAIC ACID MONOMETHYL ESTER[J].Speciality Petrochemicals,2009,26(3). | |
| Authors: | Amatjan Sawut Wumanjiang Eli Ismayil Nurulla |
| Abstract: | Preparation of azelaic acid monomethyl ester by ozonolysis reaction from oleic acid methyl ester was studied.Using the mixture of acetic acid and hexane as solvent,the effects of factors such as material ratios,ozonolysis temperature,oxygenolysis temperature and oxygenolysis time on the reaction were examined.The obtained optimum conditions were:V(oleic acid methyl ester):V(compound solvent)=1:4,ozonation temperature 10-13℃,oxygenolysis temperature 90-95℃and oxygenolysis time 2.5 h.The crude product was purified by molecular distillation.Under above conditions, the yield was above 78%,with the purity≥96%.The product was characterized by IR,~1H NMR and GC-MS. |
| Keywords: | oleic acid methyl ester ozonation azelaic acid monomethyl ester molecular distillation |
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