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微观表征法研究煤矸石改性水泥砂浆水化机理
引用本文:徐子芳,张明旭,闵凡飞.微观表征法研究煤矸石改性水泥砂浆水化机理[J].硅酸盐通报,2010,29(1).
作者姓名:徐子芳  张明旭  闵凡飞
作者单位:安徽理工大学材料科学与工程学院,淮南,232001
基金项目:安徽省教育厅自然基金资助项目(KJ2008B274)
摘    要:在水泥胶砂中掺入适当配比的煤矸石可以增加水泥砂浆的强度,尤其是早期强度。与不添加煤矸石的基准砂浆相比,煤矸石的掺量为9%时,砂浆3d抗压强度提高1.0MPa,28d抗压强度提高2.0MPa。XRD、TGA-DTA和SEM分析证实:加入煤矸石促进了水泥砂浆7d早期水化反应,生成水化产物钙矾石、C-S-H凝胶、AFm和氢氧化钙,且水化产物的数量亦不同,各产物的晶型结构也不相同,改性后水化产物增多,水化速率加快,因而影响砂浆的宏观力学强度。

关 键 词:煤矸石  水泥砂浆  性能分析  微观结构  

Study on the Hydration Mechanism of Coal Gangue Modified Cement Mortar by Microstructure Characterization
XU Zi-fang,ZHANG Ming-xu,MIN Fan-fei.Study on the Hydration Mechanism of Coal Gangue Modified Cement Mortar by Microstructure Characterization[J].Bulletin of the Chinese Ceramic Society,2010,29(1).
Authors:XU Zi-fang  ZHANG Ming-xu  MIN Fan-fei
Affiliation:School of Material Science and Engineering;Anhui University of Science and Technology;Huainan 232001;China
Abstract:The addition of suitable amount of coal gangue to cement mortar may increase cement mortar strength. When the content of coal gangue is 9%,the compressive strengths at 3 and 28 d increased 1.0 MPa and 2.0 MPa,respectively. The analysis by XRD,TGA-DTA and SEM showed that the addition of coal gangue prompted the hydration reaction at early stage of 7 days. The hydration products are AFt,C-S-H,AFm and Ca(OH)2. These hydration products and crystal structures are different. After modification,hydration products ...
Keywords:coal gangue  cement mortar  performance analysis  microstructure  
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