Electrosynthesis using a fluoride ion mediator. Part V: Fluoride ion mediated anodic methoxylation and acetoxylation of thiazolidines, 1,3-oxathiolanes, and 1,3-dithiolanes |
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Authors: | Daisuke Baba |
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Affiliation: | Department of Electronic Chemistry, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama 226-8502, Japan |
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Abstract: | Anodic methoxylation and acetoxylation reactions of five membered cyclic sulfides such as thiazolidines, 1,3-oxathiolanes and 1,3-dithiolanes, which have been reported to not always undergo the Pummerer reaction, were successfully carried out by using a fluoride ion mediator. |
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Keywords: | Anodic substitution Fluoride ion Mediator Thiosugar Regioselectivity |
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