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Electrosynthesis using a fluoride ion mediator. Part V: Fluoride ion mediated anodic methoxylation and acetoxylation of thiazolidines, 1,3-oxathiolanes, and 1,3-dithiolanes
Authors:Daisuke Baba
Affiliation:Department of Electronic Chemistry, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama 226-8502, Japan
Abstract:Anodic methoxylation and acetoxylation reactions of five membered cyclic sulfides such as thiazolidines, 1,3-oxathiolanes and 1,3-dithiolanes, which have been reported to not always undergo the Pummerer reaction, were successfully carried out by using a fluoride ion mediator.
Keywords:Anodic substitution  Fluoride ion  Mediator  Thiosugar  Regioselectivity
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