有机硅环氧树脂及其复合材料的光固化研究

通过研究光引发剂的种类、用量、光照时间和光敏剂等对树脂光固化后凝胶率的影响,确定了ES-06有机硅环氧树脂光固化的工艺条件,在质量分数分别为5%的二苯基碘鎓六氟磷酸盐光引发剂和5.5%的多元醇链转移剂作用下,光照10 min后紫外光开环聚合产物的凝胶率可达80%.利用湿法手工铺叠工艺和光固化技术,制备了玻璃布/有机硅环氧树脂复合材料,测试并分析比较了有机硅环氧和双酚A环氧复合材料的力学性能.结果表明,光固化有机硅环氧树脂基复合材料层板的拉伸强度和层间剪切强度较优,分别为158.5 MPa和9.9MPa,而两者的弯曲性能和拉伸模量相当.

UV curing silicon-containing epoxy resin and its glass cloth reinforced composites

A UV-curable cationic silicon-containing epoxy resin formulation was developed. The gel conversion of the cured resin after 10-min UV irradiation reached 80% in the presence of 5% diaryliodonium salt photoinitiator and 5.5% polyol chain transfer agent by cationic ring-opening polymerization. The glassdoth-reinforced composites were fabricated with the silicon-containing epoxy resin using the wet lay-up technique and UV irradiation. The mechanical properties of the composites were evaluated. Compared with glass cloth reinforced bisphenol A epoxy resin matrix composites, the silicon-containing epoxy resin matrix composites possessed higher tensile strength and interlayer shear strength which was .158.SMPa and 9.9MPa respectively while other mechanical properties such as flexural property and tensile modulus were similar.