Novel Supramolecular Square Grid-Like Structure: Synthesis and Characterization of [(Me3Sn)2CrO4] |
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| Authors: | Fenghui Liu Wanzhi Chen Xiaozeng You |
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| Affiliation: | 1. The State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Department of Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China
2. Villa Sanberunal 405, Shinjuku 7-3-5, Shinjuku Ku, Tokyo, Japan
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| Abstract: | Reactions of K2Cr2O7 and K2CrO4 with Me3SnCl yielded (Me3Sn)2CrO4] (1) and (Me3Sn)2CrO4?(Me3SnOH)] (2), respectively, which were characterized by elemental analysis, 1H-NMR spectroscopy, and an X-ray diffraction study. Compound 1 shows a novel square grid-like structure consisting of CrO4 2? and Me3Sn+ ions, whereas 2 exhibits a three-dimensional structure composed of CrO4 2?, Me3Sn+, and (Me3Sn)2SnOH]+ ions. |
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