| 时效温度对化学刻蚀304不锈钢超亲水稳定性的影响 |
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| 引用本文： | 王岩伟,朱光明,赵丕阳,闵范磊,曹晓琳,丁明凯,殷继丽,翟晓庆,郭娜娜. 时效温度对化学刻蚀304不锈钢超亲水稳定性的影响[J]. 表面技术, 2018, 47(1): 27-32. DOI: 10.16490/j.cnki.issn.1001-3660.2018.01.005 |
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| 作者姓名： | 王岩伟 朱光明 赵丕阳 闵范磊 曹晓琳 丁明凯 殷继丽 翟晓庆 郭娜娜 |
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| 作者单位： | 山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000;山东理工大学 机械工程学院,山东 淄博,255000 |
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| 基金项目： | 国家自然科学基金（51104096） |
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| 摘 要： | 目的利用化学刻蚀、化学氧化方法在304不锈钢表面制备微纳米结构并实现超亲水性质,改变时效处理温度,研究亲水表面润湿性的稳定程度。方法以2 mol/L的FeCl_3溶液、HCl、H_2O_2按照15:1:1的体积比混合得到刻蚀溶液,氧化液采用CrO_3与H_2SO_4的混合溶液。刻蚀完成后,通过接触角测量仪(OCA15EC)、场发射扫描电子显微镜(FE-SEM)及自带的能谱仪(EDS)表征试样表面的接触角、微纳米级表面形貌及试样表面元素,并分析不同处理条件下润湿性的变化规律。结果在本征润湿角为45°左右的304不锈钢基体上,通过化学刻蚀、化学氧化的复合处理方法可以获得超亲水表面。常温条件下,试样能够维持一定时间的超亲水性质。高温时效处理后,超亲水表面的润湿性发生变化,经400℃时效处理后,重新获得超亲水特性。结论该方法较易在耐腐蚀基体不锈钢表面制备微纳米结构,对基体表面润湿性产生影响。
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| 关 键 词： | 超亲水 化学刻蚀 化学氧化 不锈钢 时效温度 |
| 收稿时间： | 2017-07-18 |
| 修稿时间： | 2018-01-20 |
Effects of Aging Temperature on Super-hydrophilic Stability of Chemical Etching 304 Stainless Steel |
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| WANG Yan-wei,ZHU Guang-ming,ZHAO Pi-yang,MIN Fan-lei,CAO Xiao-lin,DING Ming-kai,YIN Ji-li,ZHAI Xiao-qing and GUO Na-na. Effects of Aging Temperature on Super-hydrophilic Stability of Chemical Etching 304 Stainless Steel[J]. Surface Technology, 2018, 47(1): 27-32. DOI: 10.16490/j.cnki.issn.1001-3660.2018.01.005 |
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| Authors: | WANG Yan-wei ZHU Guang-ming ZHAO Pi-yang MIN Fan-lei CAO Xiao-lin DING Ming-kai YIN Ji-li ZHAI Xiao-qing GUO Na-na |
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| Affiliation: | School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China,School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China and School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, China |
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| Abstract: | The work aims to study stability of hydrophilic surface wettability as a function of aging temperature by prepar-ing micro-nano structures and realizing super-hydrophilicity on the surface of 304 stainless steel by chemical etching and chem-ical oxidation. An etching solution was obtained by mixing 2 mol/L FeCl3solution, HCl and H2O2in a volume ratio of 15:1:1. Contact angle, micro-nano surface morphology and surface elements of the sample were characterized with contact angle mea-suring instrument, field emission scanning electron microscope and self-contained energy dispersive spectrometer, and change rule of wettability in different treatment conditions was analyzed. The super-hydrophilic surface could be obtained by chemical etching and chemical oxidation on the 304 stainless steel substrate with intrinsic wetting angle of 45°. Super-hydrophilicity of the sample could be maintained for a certain period of time at normal temperature. Wettability of the super-hydrophilic surface changed after aging treatment at high temperature, and the super-hydrophilicity was recovered after aging treatment at 400 . ℃The method facilitates preparation of micro-nanostructure on stainless steel surface of corrosion resistant substrate, and has ef-fects on wettability of substrate surface. |
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| Keywords: | super-hydrophilic chemical etching chemical oxidation stainless steel aging temperature |
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