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Ring compression properties of SiCf/SiC composites prepared by chemical vapor infiltration
Authors:Yue Li  Zhaoke Chen  Ruiqian Zhang  Zongbei He  Haoran Wang  Linjing Wang  Guiliang Liu  Daogui Fu  Xiang Xiong
Affiliation:1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;2. Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu 610213 China
Abstract:SiC fiber reinforced SiC matrix (SiCf/SiC) composites prepared by chemical vapor infiltration are one of promising materials for nuclear fuel cladding tube due to pronounced low radioactivity and excellent corrosion resistance. As a structure component, mechanical properties of the composites tubes are extremely important. In this study, three kinds of SiCf preform with 2D fiber wound structure, 2D plain weave structure and 2.5D shallow bend-joint structure were deposited with PyC interlayer of about 150–200?nm, and then densified with SiC matrix by chemical vapor infiltration at 1050?°C or 1100?°C. The influence of preform structure and deposition temperature of SiC matrix on microstructure and ring compression properties of SiCf/SiC composites tubes were evaluated, and the results showed that these factors have a significant influence on ring compression strength. The compressive strength of SiCf/SiC composites with 2D plain weave structure and 2.5D shallow bend-joint structure are 377.75?MPa and 482.96?MPa respectively, which are significantly higher than that of the composites with 2D fiber wound structure (92.84?MPa). SiCf/SiC composites deposited at 1100?°C looks like a more porous structure with SiC whiskers appeared when compared with the composites deposited at 1050?°C. Correspondingly, the ring compression strength of the composites deposited at 1100?°C (566.44?MPa) is higher than that of the composites deposited at 1050?°C (482.96?MPa), with a better fracture behavior. Finally, the fracture mechanism of SiCf/SiC composites with O-ring shape was discussed in detail.
Keywords:Chemical vapor infiltration  Microstructure  Ring compression strength  Fracture mechanism
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