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新型吸附剂铜基铂对放射性碘的吸附研究
引用本文:许晓飞,王刚,马红利,董鹏,傅红宇,罗文博. 新型吸附剂铜基铂对放射性碘的吸附研究[J]. 同位素, 2014, 27(3): 157-161. DOI: 10.7538/tws.2014.27.03.0157
作者姓名:许晓飞  王刚  马红利  董鹏  傅红宇  罗文博
作者单位:原子高科股份有限公司,北京102413
摘    要:通过测定铜基铂对放射性碘的吸附和洗脱性能,探索铂对铜基铂(PCC)性能的影响。在含有亚硫酸钠的稀硫酸介质中,采用柱层析技术测定了PCC对I-的吸附容量、洗脱效率。结果表明:氯铂酸用量在2mL时合成的PCC对I的工作吸附容量可达0.224mg/g(I与Cu的质量比),吸附效率大于99%。以15mL0.1mol/L氢氧化钠溶液洗脱铜基铂,洗脱效率在95%以上。

关 键 词:铜基铂  选择性吸附  放射性碘

Study of New Adsorbent Platinum-coated Copper for Radioactive Iodine
XU Xiao-fei,WANG Gang,MA Hong-li,DONG Peng,FU Hong-yu,LUO Wen-bo. Study of New Adsorbent Platinum-coated Copper for Radioactive Iodine[J]. Isotopes, 2014, 27(3): 157-161. DOI: 10.7538/tws.2014.27.03.0157
Authors:XU Xiao-fei  WANG Gang  MA Hong-li  DONG Peng  FU Hong-yu  LUO Wen-bo
Affiliation:HTA CO.,LTD., Beijing 102413,China
Abstract:The adsorption and elution properties of platinum-coated copper (PCC) for radioactive iodine have been revealed and the effects of platinum on the performance of PCC were explored. In sulfuric acid medium containing sodium sulfite, the adsorption capacity, elution efficiency of PCC and the effect of platinum on PCC were determined by column chromatography. The results showed that the adsorption capacity of PCC prepared with 2 mL ehloroplatinie acid or more for I was up to 0. 224 mg/g with the adsorption efficiency of more than 990% while the elution efficiency was more than 95G by 15 mL 0.1 mol/L sodium hydroxide solution.
Keywords:platinum-coated copper selective adsorption radioactive iodine
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