| Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen |
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| 作者姓名： | 纪红兵 黄月英 钱宇 王婷婷 张美英 |
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| 作者单位： | [1]School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China [2]Analytical and Testing Center, South China University of Technology, Guangzhou 510640, China |
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| 摘 要： | An efficient reduction system of benzaldehyde with hydrogen under ambient pressure was developed using facile NiO catalyst. The non-aromatic solvents such as cyclohexane, tetrahydrofuran （THF） and n-hexane, and the additive with strong basicity e.g. KOH, were necessary for smooth conversion of the substrate. That the catalyst can be recovered and reused for nine times without loss of catalytic activity indicates that this catalyst is a recyclable one for benzaldehyde reduction.
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| 关 键 词： | 常压氢气 氧化镍催化剂 液相还原 羰基化合物 苯甲醛 |
| 收稿时间： | 2005-04-11 |
| 修稿时间： | 2005-04-112005-11-15 |
Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen |
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| Hongbing JI, Yueying HUANG, Yu QIAN, Tingting WANG,Meiying ZHANG.Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen[J].Chinese Journal of Chemical Engineering,2006,14(1):118-121. |
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| Authors: | Hongbing JI Yueying HUANG Yu QIAN Tingting WANG Meiying ZHANG |
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| Affiliation: | aSchool of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China;bAnalytical and Testing Center, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | An efficient reduction system of benzaldehyde with hydrogen under ambient pressure was developed using facile NiO catalyst. The non-aromatic solvents such as cyclohexane, tetrahydrofuran (THF) and n-hexane, and the additive with strong basicity e.g. KOH, were necessary for smooth conversion of the substrate. That the catalyst can be recovered and reused for nine times without loss of catalytic activity indicates that this catalyst is a recyclable one for benzaldehyde reduction. |
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| Keywords: | reduction nickel oxide benzaldehyde recyclable catalyst |
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