电解质溶液热力学进展

本文从工程应用的角度出发,综述了近年来电解质溶液热力学的理论、活度系数的半经验模型及各类相平衡计算方法。讨论了化工界较为关心的含盐溶液汽液平衡关联和预测的进展问题。

Progress on the Thermodynamics of Electrolyte So(?)utions

In view of engineering applications the latest achievements in electrolyte solution thermodynamics were reviewed including the theories, the semiemperical models and the methods for calculating the different phase equilibria. The progress on the correlation and prediction of vapor-liquid equilibria for salt-containing systems, which is interesting to the chemical engineers, was discussed.