| 甲基丙烯酸甲酯的绿色催化合成进展 |
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| 引用本文： | 胡玉才. 甲基丙烯酸甲酯的绿色催化合成进展[J]. 精细化工中间体, 2005, 35(5): 15-17 |
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| 作者姓名： | 胡玉才 |
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| 作者单位： | 烟台师范学院,化学与材料科学学院,山东,烟台,264025 |
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| 基金项目： | 山东省优秀中青年科学家科研奖励基金（2004BS08001）和烟台师范学院自然科学基金（032913,042901）资助项目 |
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| 摘 要： | 合成甲基丙烯酸甲酯(MMA)的传统方法丙酮氰醇法(ACH法)存在着原料毒性大、副反应 多,工艺流程复杂、原子利用率低的缺点。绿色催化合成MMA的方法主要有改进的ACH法、异丁烯 法、丙炔法、丙烯法、甲基丙烯醛氧化酯化法等,这些方法均符合绿色化学的要求。笔者对这几种绿色合 成工艺以及所用催化剂的研究概况进行了综述。
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| 关 键 词： | 甲基丙烯酸甲酯 绿色化学 催化 |
| 文章编号： | 1009-9212(2005)05-0015-03 |
| 收稿时间： | 2005-07-05 |
| 修稿时间： | 2005-07-05 |
The Developnent of Green Catalytic Synthesic metlods of Methyl Methacrylate |
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| HU Yu-cai. The Developnent of Green Catalytic Synthesic metlods of Methyl Methacrylate[J]. Fine Chemical Intermediates, 2005, 35(5): 15-17 |
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| Authors: | HU Yu-cai |
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| Abstract: | Traditional acetone cyanohydrine method (ACH) for the synthesis of methyl methacrylate (MMA) has many disadvantages such as toxic raw material, many side reactions, complicated process and low atom efficiency. The methods for green catalytic synthesis of MMA mainly include the improved ACH. isobutene method, methyl acetylene method, propene method, and oxidative esterification of methacrolein.which meet demands of green chemistry. Research generalization of these green synthesis process and the corresponding catalysts is reviewed in this paper. |
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| Keywords: | methyl methacrylate (MMA) green chemistry catalysis |
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