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Investigation of the main structural units in Bi2O3-TiO2solutions
Authors:T. M. Bruton
Affiliation:1. Mullard Research Laboratories, Redhill, Surrey, UK
Abstract:To investigate a possible correlation between observed crystal growth phenomena and the structure in the liquid phase of Bi2O3-TiO2 solutions, densities and viscosities have been measured and interpreted by the hard sphere model for liquids. The main flow units are probably BiO 2 ? and BiO+ with some Ti complex formation which increases with increasing TiO2. A change in the complex formation occurs at 12 mol % TiO2.
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