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阻燃剂双(对-羧苯基)苯基氧化膦的合成工艺研究
引用本文:戈鹏,李巧玲,汪建红,王亚昆,张丽萍. 阻燃剂双(对-羧苯基)苯基氧化膦的合成工艺研究[J]. 应用化工, 2006, 35(5): 379-381
作者姓名:戈鹏  李巧玲  汪建红  王亚昆  张丽萍
作者单位:1. 中北大学,化学系,山西,太原,030051
2. 中国兵器工业新技术推广研究所,北京,100089
基金项目:山西省高等学校科研开发基金;山西省自然科学基金
摘    要:双(对-羧苯基)苯基氧化膦是20世纪90年代研究开发的新型磷系阻燃剂,目前尚处于实验开发阶段。简述了该阻燃剂的各种合成方法,评价了这些方法的优缺点,并提出新的合成方案,具有成本低、周期短、环境污染小等优点,符合阻燃剂绿色无卤化的发展方向。

关 键 词:双(对-羧苯基)苯基氧化膦  阻燃剂  合成
文章编号:1671-3206(2006)05-0379-03
收稿时间:2006-03-21
修稿时间:2006-03-21

Study on synthesizing technology of flame retardant bis (4-carboxyphenyl) phenyl phosphine oxide
GE Peng,LI Qiao-ling,WANG Jian-hong,WANG Ya-kun,ZHANG Li-ping. Study on synthesizing technology of flame retardant bis (4-carboxyphenyl) phenyl phosphine oxide[J]. Applied chemical industry, 2006, 35(5): 379-381
Authors:GE Peng  LI Qiao-ling  WANG Jian-hong  WANG Ya-kun  ZHANG Li-ping
Affiliation:1. Chemistry Department, North University of China, Taiyuan 030051, China; 2. China North Advanced Technology Generalization Institute,Beijing 100089 ,China
Abstract:Bis(4-carboxyphenyl) phenyl phosphine oxide was a novel phosphorous flame retardant which was first prepared in 1990s,at present,it was still at the stage of experimentation.Some synthesizing methods of the flame retardant were referred,and their advantages and disadvantages were appraised.A novel synthesizing program was drawn up,which has the advantages,such as low-cost,short-cycle,light pollution,in accord with the developing orientation of free-halogen for the flame retardant.
Keywords:bis(4-carboxyphenyl) phenyl phosphine oxide  flame retardant  synthesis
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