| 带取代(艹卓)酮基的中性生色氮杂15-冠-5-醚的合成及其络合性质的研究 |
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| 引用本文： | 张晓鹏,丛志奇,尹炳柱,吴峰.带取代(艹卓)酮基的中性生色氮杂15-冠-5-醚的合成及其络合性质的研究[J].延边大学理工学报,2005,31(1). |
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| 作者姓名： | 张晓鹏 丛志奇 尹炳柱 吴峰 |
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| 作者单位： | 延边大学理工学院化学系 吉林延吉133002
(张晓鹏，丛志奇，尹炳柱)，吉林交通职业技术学院 吉林长春130012(吴峰) |
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| 基金项目： | 国家自然科学基金资助项目(20262006) |
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| 摘 要： | 通过艹卓酚酮甲基醚的取代衍生物与氮杂15 冠 5 醚的缩合反应,除了得到文献已报道的化合物2a以外,还得到了两种新的带取代艹卓酮环的中性生色氮杂15 冠 5 醚.用1HNMR和MS表征了其结构,并利用UV Vis光谱评价了三种化合物对Na 、K 、NH4 的络合性能.
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| 关 键 词： | 艹卓酚酮甲基醚 生色氮杂15冠5醚 络合性能 合成 |
Synthesis and complexation properties of neutral chromogenic aza-15-crown-5-ether having substituted troponyl group |
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| ZHANG Xiao-peng,CONG Zhi-qi,YIN Bing-zhu,WU Feng.Synthesis and complexation properties of neutral chromogenic aza-15-crown-5-ether having substituted troponyl group[J].Journal of Yanbian University (Natural Science),2005,31(1). |
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| Authors: | ZHANG Xiao-peng CONG Zhi-qi YIN Bing-zhu WU Feng |
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| Affiliation: | ZHANG Xiao-peng~1,CONG Zhi-qi~1,YIN Bing-zhu~1,WU Feng~2 |
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| Abstract: | Under neutral conditions, three new aza-15-crown-5-ether derivatives having chromogenic troponyl as a functional pendant group were prepared by condensation reactions of substituted tropolone methyl ether derivatives with aza-15-crown-5-ether and their structure were comfirmed by ()~1H NMR spectrum and MS spectrum. The complexation behaviors of new compounds for Na~ , K~ and NH_4~ were estimated through UV spectral analysis. |
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| Keywords: | Tropolone methyl ether Chromogenic aza-15-crown-5-ether Complexation Synthesis |
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