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| 苯酚分子印迹聚合物及印迹膜的制备与性能研究 | |
| 引用本文： | 周皓,邬宇茜,夏建军,王明锋,朱秀芳,曹秋娥,丁中涛. 苯酚分子印迹聚合物及印迹膜的制备与性能研究[J]. 云南化工, 2012, 39(3): 1-5,9 |
| 作者姓名： | 周皓 邬宇茜 夏建军 王明锋 朱秀芳 曹秋娥 丁中涛 |
| 作者单位： | 1. 云南大学化学科学与工程学院,教育部自然资源药物化学重点实验室,云南昆明650091 2. 云南大学化学科学与工程学院,教育部自然资源药物化学重点实验室,云南昆明650091 红云红河烟草集团技术中心,云南昆明650202 3. 红云红河烟草集团技术中心,云南昆明,650202 |
| 基金项目： | 国家自然科学基金(20964005);教育部新世纪优秀人才支持计划(NCET-08-0925);云南省中烟公司资助项目(2009FL03) |
| 摘 要： | 以苯酚为印迹分子,2-乙烯基吡啶为功能单体,采用正交试验设计,改变功能单体种类、致孔溶剂种类、交联剂用量等影响因素,分别制备了9个苯酚分子印迹聚合物（MIP1-9）,优化得到了印迹聚合物制备的最佳条件,并在此基础上制备了苯酚印迹复合膜（MIM）。对优化得到的MIP4及MIM分别进行了吸附和渗透特性研究。结果表明,实验制备的MIP4及MIM具有一定的选择性分离富集苯酚的性能。 |
| 关 键 词： | 分子印迹技术 聚合物（膜） 苯酚 |
Preparation and Property of Phenol Molecular Imprinted Polymer/Membrane |
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| ZHOU Hao,WU Yu-xi,XIA Jian-jun,WANG Ming-Feng,ZHU Xiu-fang Zhu,CAO Qiu-e,DING Zhong-tao. Preparation and Property of Phenol Molecular Imprinted Polymer/Membrane[J]. Yunnan Chemical Technology, 2012, 39(3): 1-5,9 | |
| Authors: | ZHOU Hao WU Yu-xi XIA Jian-jun WANG Ming-Feng ZHU Xiu-fang Zhu CAO Qiu-e DING Zhong-tao |
| Affiliation: | 1(1.Key Laboratory of Medicinal Chemistry for Nature Resource,Ministry of Education;School of Chemical Science and Technology,Yunnan University,Kunming 650091,China 2.Technology Center,Hongyun-Honghe Tobacco(Group) Co.Ltd.,Kunming 650202,China) |
| Abstract: | Using 2-VP as functional monomer,nine phenol imprinted polymers(MIP1-9) were synthesized by orthogonal design considering 3 factors: the kind of porogen solvent,the dosage of functional monomer and that of cross linker.The optimum MIP4 was furthermore used to study its adsorption property.On the basis of study on MIP,a phenol imprinted membrane(MIM) was prepared,and its premeation characterization was also investigated.The results showed that the optimum MIP4 and MIM had a certain selective separation and enrichment property to phenol. |
| Keywords: | Molecularly imprinted technology Orthogonal experimental design Phenol. |
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