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Thermally induced porous carbon nanofibers for electrochemical capacitor electrodes from phenylsilane and polyacrylonitrile blend solutions
Authors:Bo-Hye Kim  Kap Seung Yang  Yun Hyuk Bang  Sung Ryong Kim
Affiliation:1. Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Vic 3122, Australia;2. Deakin University, Geelong, Institute for Frontier Materials, Waurn Ponds, Victoria 3216, Australia;3. Middle Technical University, Al-Za''franiya, Baghdad 10074, Iraq;4. CSIRO Manufacturing, Waurn Ponds, Victoria 3216, Australia
Abstract:This work focuses on preparations of porous carbon composite nanofibers (CCNFs) with silicon-containing compounds and the introduction of a high specific surface area through the creation of pores by a simple thermal treatment. Blends of phenylsilane (PS) solutions at various concentrations and polyacrylonitrile (PAN) were electrospun into nanofibers. This process was followed by carbonization at 800 °C to create CCNFs with diameters of 60–200 nm and a high specific surface area of over 800 m2/g. The specific capacitance of the electrode in 6 M KOH solution was extraordinarily high (180 F/g).
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