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Formation and characterization of zinc oxide nanowires grown on hexagonal-prism microstructures
Authors:SH Mousavi  H Haratizadeh  AH Kitai
Affiliation:1. Physics Department, Shahrood University of Technology, Shahrood, Iran;2. Department of Engineering Physics, McMaster University, Hamilton, Ontario L8S 2N5, Canada;1. Department of Medicinal Chemistry, Virginia Commonwealth University, 800 East Leigh Street, Richmond, VA 23298, USA;2. Department of Anatomy & Neurobiology, Virginia Commonwealth University, 1217 East Marshall Street, Richmond, VA 23298, USA;3. Department of Pharmacology and Toxicology, Virginia Commonwealth University, 410 North 12th Street, Richmond, VA 23298, USA;4. Veterinary Microbiology and Pathology, Washington State University, Pullman, WA 99164, USA;1. Institute of Electronic Information Technology, Taiyuan University of Science and Technology, Taiyuan 030024, China;2. North University of China, Key Lab on Instrumentation Science & Dynamic Measurement of the Ministry, Taiyuan 030051, China;3. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, CAS, Taiyuan 030001, China;1. Voevodsky Institute of Chemical Kinetics and Combustion SB RAS, Institutskaya str., 3, 630090 Novosibirsk, Russia;2. Institute for Water and Environmental Problems SB RAS, Morskoi avenue., 2, 630090 Novosibirsk, Russia;3. Novosibirsk State Pedagogical University, Viluiskaya str., 28, 630126 Novosibirsk, Russia;4. Department of Physics, University of Helsinki, P.O.Box 64 (Gustaf Hällstrцmin katu 2a) FI-00014, Finland;1. Department of Chemistry, Aligarh Muslim University, Aligarh 202 002, India;2. Diversity Oriented Synthesis Laboratory, Indian Institute of Chemical Technology, Hyderabad 500 607, India
Abstract:In this paper, zinc oxide (ZnO) micro- and nano-structures were synthesized through a chemical vapor deposition route. X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), and scanning electron microscopy (SEM) were used to study the samples’ phase, composition, purity, and structure. XRD analysis confirmed the formation of the wurtzite phase in all samples. SEM images revealed the formation of hexagonal-prism microstructures of ZnO. After we changed the conditions, nano-wires 40–50 nm in diameter appeared on these hexagonal-prism microstructures. Further, we investigated the photoluminescence properties of these structures at room temperature. The modified structures showed UV emission and strong blue-green photoluminescence line due to near-band emission and oxygen vacancies respectively.
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