Heterocyclic compounds derived from aliphatic amines |
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Authors: | T. A. Foglia G. Maerker |
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Affiliation: | (1) Eastern Utilization Research and Development Division, 19118 Philadelphia, Pennsylvania |
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Abstract: | The photolytic rearrangement of N-chloroamines derived from secondary fatty amines, such as N-methyloctadecylamine, has been investigated. The intermediate δ- or ε-chloroamines, or both, were not isolated from the reaction medium but were converted directly to their corresponding N-methyl-2-alkylpyrrolidine or piperidine analogs, or both, by treatment with alkali. The synthetic utility of this reaction has been extended to include the two functionally substituted secondary amines, N,N-dimethylazelaylamine and methyl 11-methylaminoundecanoate. The yields of isolated pure products are in the range of 50–80%. Presented at the AOCS Meeting, New York, October, 1968. ARS, USDA. |
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