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多壁碳纳米管/环氧树脂纳米复合材料的固化动力学研究
引用本文:张娇霞,郑亚萍,张爱波,宁荣昌.多壁碳纳米管/环氧树脂纳米复合材料的固化动力学研究[J].中国胶粘剂,2007,16(7):1-5.
作者姓名:张娇霞  郑亚萍  张爱波  宁荣昌
作者单位:西北工业大学理学院应用化学系,陕西,西安,710072
基金项目:西北工业大学第三批英才计划;西北工业大学校科研和教改项目
摘    要:采用熔融混合法向低粘度的环氧树脂中添加适量的多壁碳纳米管,制备新型纳米复合材料,并采用傅里叶变换红外光谱仪(FT-IR)测试转化率,采用差示扫描量热法(DSC)研究多壁碳纳米管/环氧树脂复合体系的固化动力学,并对纳米复合材料的力学性能进行研究。结果表明:多壁碳纳米管加入环氧树脂复合体系后,对固化反应有催化作用,固化反应速率增大,转化率提高,而复合体系的力学性能却有所下降,玻璃化转变温度变化不大。

关 键 词:多壁碳纳米管  环氧树脂  纳米复合材料  固化动力学
文章编号:1004-2849(2007)07-0001-05
修稿时间:2007-04-13

Study on curing dynamical data of multi-walls carbon nanotubes(MWNTs)/epoxy resin nanocomposites
ZHANG Jiao-xia,ZHENG Ya-ping,ZHANG Ai-bo,NING Rong-chang.Study on curing dynamical data of multi-walls carbon nanotubes(MWNTs)/epoxy resin nanocomposites[J].China Adhesives,2007,16(7):1-5.
Authors:ZHANG Jiao-xia  ZHENG Ya-ping  ZHANG Ai-bo  NING Rong-chang
Abstract:MWNTs/epoxy nanocomposites were prepared with different content carbon nanotubes and epoxy resin through melt methods.Fourier transform infrared spectrum(FT-IR)was employed to test the conversion rate of the nanocomposites.The curing behaviors of MWNTs/epoxy nanocomposites had been studied by differential scanning calorimetry(DSC) technique.As a result,with MWNTs incorporated into the epoxy resin curing system,the cure rate and conversion rate were increased,but mechanical properties of nanocomposites decreased and glass transition temperature had no obviously change.
Keywords:multi-walls carbon nanotubes  epoxy resin  nanocomposites  curing dynamical data
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