Carbothermic reduction of llmenite (FeTiO3) and rutile (TiO2) |
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Authors: | N J Welham and J S Williams |
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Affiliation: | (1) the Electronic Materials Engineering, Research School of Physical Sciences and Engineering, Australian National University, 2600 Canberra, ACT, Australia |
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Abstract: | The mechanically activated carbothermic reduction mechanism of ilmenite has been examined by a combination of steady-state
and dynamic thermal techniques coupled with X-ray diffraction. The reaction was found to proceed via an initial, rapid reduction to elemental iron and rutile, which was followed by a slow reduction of rutile to a series of
oxides of the general formula Ti
n
O2n−1 until Ti3O5 was formed, which was found to be relatively stable. Iron was probably incorporated into the Ti
n
O2n−1 lattice only for n>3, forming mixed oxides of uncertain composition. The formation of TiC was evident at temperatures as low as 1100 °C, but
the rate of reaction was extremely slow, presumably due to a solid-state diffusion limitation. Increasing the temperature
gave increasing conversion of TiO2 to TiC until it was the only confirmed product. The effect of iron on the later stages of reduction was removed by examining
the reduction of pure rutile. It was found that the reduction of Ti3O5 was enhanced by the presence of iron. The separation of iron from the titanium product proved to be high, with > 90 pct of
iron removed after the initial reduction. The iron removal increased slowly to almost 100 pct when elemental iron and titanium
carbide were the products. |
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Keywords: | |
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