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The reaction occurring between gaseous CF4 and oxides dissolved in different molten fluorides. Some practical aspects
Authors:C E Castellano  A J Calandra
Affiliation:(1) Research and Development, Department of Electrochemical Processes, ALUAR Aluminio Argentino SAIC, Puerto Madryn, Chubut, Argentina
Abstract:When CF4 is bubbled through molten fluorides containing dissolved oxides within the range 900–1020° C, a chemical reaction takes place which decreases the oxide concentration and yields CO2 and F ions. The possibility of the reaction between the CF4 evolved at the anode and dissolved alumina, occurring during the anode effect in aluminium reduction cells, is discussed. This reaction provides a simple and convenient method for removing oxides and hydroxides from molten fluorides.
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