The insensitive compound bis(nitrofurazano)furazan (BNFF) with high energy‐density was synthesized by three‐step reactions and fully characterized. The key reduction reaction was discussed. BNFF has a high crystal density (1.839 g cm?3) and a low melting point (82.6 °C). BNFF is insensitive to impact and friction and has similar detonation velocity (8680 m s?1) and detonation pressure (36.1 GPa) compared to RDX.