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Preparation of a high hydrophobic aluminium surface by double zincating process
Authors:Nagarjuna Reddy Paluvai  Hassan Hafeez  Dong-Ho Han  Heon-Yul Ryu  Choon-Soo Lee
Affiliation:1. Department of Bionanotechnology, Hanyang University ERICA, Ansan, Republic of Korea;2. Materials Engineering, Hanyang University ERICA, Ansan, Korea;3. Automotive R&4. D Division, Hyundai Motor Group, Hwaseong, Korea
Abstract:In this present study, an efficient method has been proposed to develop a high hydrophobic zincated coating on the eva-core aluminium (Al) alloy surface. The double zincating method (Z2) was utilized to develop the required roughness on the Al surface. To control the surface energy, lauric acid (LA) was coated on the surface using the liquid self-assembled monolayers (L-SAMs) method. Surface morphology, the chemical composition of the treated and untreated Al alloy has been studied using scanning electron microscopy (SEM), atomic force microscopy (AFM), optical microscopy and X-ray diffraction (XRD), respectively. The hydrophobicity of the substrates has also been analysed using a contact angle measurement (CA). AFM micrographs show the surface roughness of the Al alloy has been drastically increased with chemical treatments from 0.071 to 0.32 μm. XRD shows the percentage crystallinity of the Al alloy is decreased with double zincating and LA coating from 56.8 to 22.7%. As a result, a high hydrophobicity of Al alloy was induced with a contact angle of 150° upon the double zincating method and L-SAMs coating.
Keywords:Double zincating  High hydrophobicity  Self-assembled monolayers
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