Ductile Phase Toughened Brittle Materials

Ductile Phase Toughened Brittle Materials

Toughening of brittle materials by the inclusion of ductile phases is governed by several important factors which include ceramic-ductile phase interfacial bond strength, physical and chemical compatibility between ceramic and ductile phase, geometry and mechanical properties of ductile phase. The present understanding of the effect of these factors on toughening is reviewed and clarified. Continuous ductile phases (network, fibre or plate) are found to be more efficient for the toughening of brittle materials than discrete ductile particles. However, ductile particle toughened brittle materials have the advantages of material homogeneity isotropy and particularly better high temperature properties. It has been demonstrated that the influence of interfacial bond strength is determined by the geometry of the ductile phase in the composites. For the comparatively continuous ductile phase, such as ductile network, fibre or plate, comparatively weak inteffocial bond strength can promote partial debonding of the brittle matrix-ductile phase intedece during crack propagation and is beneficial for toughening. For discrete particulate ductile phase toughened brittle materials, the small gauge length of the ductile phase often results in the ductile phase pull-out during crack propagation which is the main limitation to toughening.Thus strong bond strength is required to ensure the bridging of the crack by the ductile phase.The coefficient of thermal expansion (CTE) mismatch between matrix and ductile phase has also been correlated with the geometry of the ductile phase. In most of the ceramic/metal systems,the CTE of the ductile metal phase is greater than that of the ceramic matrix. In the case of ductile network, fibre or plate, the residual stress created by the CTE mismatch can contribute to toughening through its influence on the initial crack opening stress while the bridging of the crack by the ductile phase is still ensured. However, for discrete ductile particles, the residual stress created by CTE mismatch is liable to cause cracks to by-pass the spherical particles, limiting the efficient use of the inherent toughness of the ductile phase. Low-modulus ductile inclusions are beneficial for the bridging of cracks by the ductile phase. Softer, more ductile inclusions are more effective for the toughening of brittle materials by particulate ductile phase