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聚氨酯合成革湿法生产废气中DMF的回收工艺
引用本文:赵舜华,宋锡瑾,裴宁,张景铸,刘书庆.聚氨酯合成革湿法生产废气中DMF的回收工艺[J].中国化学工程学报,2008,16(3):461-464.
作者姓名:赵舜华  宋锡瑾  裴宁  张景铸  刘书庆
作者单位:1. Zhejiang Hexin Industry Group Co., Jiaxing 314003, China;2. Department of Chemical&Biochemical Engineering, Zhejiang University, Hangzhou 310027, China;3. Yantai Dongjie Environmental Protection Machine Engineering Co., Yantai 264002, China
摘    要:A new recovery technology is developed to recycle N,N-dimethyl formamide (DMF) in waste gas from wet type polyurethane synthetic leather industry. Given that the concentration of DMF in waste gas was as low as 325.6- 688.3 mg·m^-3, it was necessary to make sure two phases contact adequately and strengthen the mass transfer by increasing contact area and enhancing the turbulence. Therefore, two-stage countercurrent absorption and two-stage fog removing system were introduced into the technology. The top section of the absorption column was filled with structured wire-ripple stainless steel packing BX500, while the lower section with sting-ripple packing CB250Y. Total height of packing material was 6 m. In addition, there were both two-stage fog removing layer and high efficiency liquid distributor at the column top. All the operating parameters, including temperature, pressure, flow rate and liquid position, could be controlled by computers without manual operation, making sure the outlet gas achieved the national emission standard that the DMF concentration should be below 40 mg·m^-3. The whole equipment could recover 237.6 t of DMF each year, with the profit up to CNY 521×10^3.

关 键 词:N  N-dimethylformamide  polyurethane  synthetic  leather  absorption  recovery  
收稿时间:2007-9-22
修稿时间:2008-3-25  

Recovery Technology of DMF from Wet Type Polyurethane Synthetic Leather Waste Gas
Shunhua ZHAO, Xijin SONG, Ning PEI, Jingzhu ZHANG,Shuqing LIU.Recovery Technology of DMF from Wet Type Polyurethane Synthetic Leather Waste Gas[J].Chinese Journal of Chemical Engineering,2008,16(3):461-464.
Authors:Shunhua ZHAO  Xijin SONG  Ning PEI  Jingzhu ZHANG  Shuqing LIU
Affiliation:1. Zhejiang Hexin Industry Group Co., Jiaxing 314003, China;2. Department of Chemical&Biochemical Engineering, Zhejiang University, Hangzhou 310027, China;3. Yantai Dongjie Environmental Protection Machine Engineering Co., Yantai 264002, China
Abstract:A new recovery technology is developed to recycle N, N-dimethyl formamide (DMF) in waste gas from wet type polyurethane synthetic leather industry. Given that the concentration of DMF in waste gas was as low as 325.6-688.3mg·m3, it was necessary to make sure two phases contact adequately and strengthen the mass transfer by increasing contact area and enhancing the turbulence. Therefore, two-stage countercurrent absorption and two-stage fog removing system were introduced into the technology. The top section of the absorption column was filled with structured wire-ripple stainless steel packing BX500, while the lower section with sting-ripple packing CB250Y. Total height of packing material was 6m. In addition, there were both two-stage fog removing layer and high efficiency liquid distributor at the column top. All the operating parameters, including temperature, pressure, flow rate and liquid position, could be controlled by computers without manual operation, making sure the outlet gas achieved the national emission standard that the DMF concentration should be below 40mg·m3. The whole equipment could recover 237.6t of DMF each year, with the profit up to CNY 521×103.
Keywords:N  N-dimethylformamide  polyurethane synthetic leather  absorption  recovery
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