Condensation polymerization of α,α′-dimethoxycarbonyl-p-xylylenedicyanide (α,α’) and oxidation to a quinodimethane polymer期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Condensation polymerization of α,α′-dimethoxycarbonyl-p-xylylenedicyanide (α,α’) and oxidation to a quinodimethane polymer

Authors:	H K Hall Jr R M Cramer J E Mulvaney

Affiliation:	(1) Department of Chemistry, University of Arizona, 85721 Tucson, AZ, USA

Abstract:	Summary , -di(methoxycarbonyl)-p-xylylenedicyanide and oxydiethanol were treated with Ti(OBu)₄ to produce a linear soluble polyester. Long reaction times led to the formation of an insoluble cross-linked polymer by reaction of the cyano groups.Treatment of the soluble polyester with N-cholrosuccinimide and Et₃N resulted in oxidation to a quinodimethane polymer.

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