| YCl_3－AECl_2（AE＝Mg，Ca，Sr，Ba）二元相图的研究 |
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| 引用本文： | 袁文霞,马淑兰,乔欣,庄卫东,邢献然,乔芝郁. YCl_3－AECl_2（AE＝Mg，Ca，Sr，Ba）二元相图的研究[J]. 金属学报, 1996, 0(2) |
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| 作者姓名： | 袁文霞 马淑兰 乔欣 庄卫东 邢献然 乔芝郁 |
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| 作者单位： | 北京科技大学，北京有色金属研究总院 |
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| 摘 要： | 用差热分析法测定了ＹＣｌ_３一ＳｒＣｌ_２体系二元相图，并用Ｘ时线衍射法验证了该二元体系中新相的生成。使用ＣＡＬＰＨＡＤ技术评估和优化了ＹＣｌ_３一ＡＥＣｌ_２（ＡＥ＝Ｍｇ，Ｃａ，Ｓｒ，Ｂａ）系列四个二元相图和热力学性质，取得了热力学性质和相图自相一致的结果。
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| 关 键 词： | 稀土氯化物，相图，热力学，熔盐 |
A STUDY ON THE YCl_3-AECl_2(AE=Mg, Ca, Sr, Ba)BINARY PHASE DIAGRAMS |
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| YUAN Wenxia, MA Shulan, QIAO Hin, ZHUANG Weidong, XING Xianran,QIAO Zhiyu. A STUDY ON THE YCl_3-AECl_2(AE=Mg, Ca, Sr, Ba)BINARY PHASE DIAGRAMS[J]. Acta Metallurgica Sinica, 1996, 0(2) |
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| Authors: | YUAN Wenxia MA Shulan QIAO Hin ZHUANG Weidong XING Xianran QIAO Zhiyu |
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| Abstract: | Phase diagram of YCl3-SrCl2 binary system has been measured by means of DTA method, and a new phase in this system was observed by X-ray diffraction. The phase diagrams and thermodynamic properties of the YCl3-AECl2(AE=Mg, Ca, Sr, Ba) systems have been assessed and optimized by using CALPHAD technique. The optimized phase diagrams are consistent with thermodynamical data. |
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| Keywords: | rare earth chloride phase diagram thermodynamics molten salt |
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