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纳米MgO制备方法对MgO/LDPE纳米复合材料介电性能的影响
引用本文:张文龙,仲利东,吴月,杨佳明,赵洪,白永平. 纳米MgO制备方法对MgO/LDPE纳米复合材料介电性能的影响[J]. 材料科学与工艺, 2014, 22(6): 113-117
作者姓名:张文龙  仲利东  吴月  杨佳明  赵洪  白永平
作者单位:1. 哈尔滨理工大学 材料科学与工程学院,哈尔滨150040; 工程电介质及其应用技术教育部重点实验室,哈尔滨150080
2. 哈尔滨理工大学 材料科学与工程学院,哈尔滨,150040
3. 哈尔滨理工大学 电气与电子工程学院,哈尔滨150080; 工程电介质及其应用技术教育部重点实验室,哈尔滨150080
4. 哈尔滨工业大学 应用化学系,哈尔滨,150001
基金项目:国家自然科学基金(50977019).
摘    要:本文对比分析了传统法和微波辅助法合成的Mg(OH)2对所制备的纳米MgO晶粒尺寸和表面形貌的影响,以及纳米MgO不同制备方法对MgO/LDPE纳米复合材料空间电荷、体积电阻率及直流击穿场强的影响.结果表明,传统法制备的纳米MgO晶粒尺寸为22.74 nm,微波辅助法制备的纳米MgO的晶粒尺寸为12.76 nm,MgO质量分数为2%时有效降低了复合材料内部空间电荷的积聚,对复合材料的体积电阻和击穿场强均有提高.

关 键 词:纳米MgO  微波辅助法  制备工艺  纳米复合材料  介电性能
收稿时间:2013-07-10

The influence of preparation methods of nano-MgO on MgO/LDPE nanocomposite dielectric properties
ZHANG Wenlong,ZHONG Lidong,WU Yue,YANG Jiaming,ZHAO Hong and BAI Yongping. The influence of preparation methods of nano-MgO on MgO/LDPE nanocomposite dielectric properties[J]. Materials Science and Technology, 2014, 22(6): 113-117
Authors:ZHANG Wenlong  ZHONG Lidong  WU Yue  YANG Jiaming  ZHAO Hong  BAI Yongping
Affiliation:College of Material Science& Engineering, Harbin University of Science and Technology, Harbin 150040, China ;Ministry of Education Key Laboratory of Engineer Dielectrics and Its Application, Harbin 150080, China;College of Material Science& Engineering, Harbin University of Science and Technology, Harbin 150040, China;College of Material Science& Engineering, Harbin University of Science and Technology, Harbin 150040, China;College of Electronic & Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China ;Ministry of Education Key Laboratory of Engineer Dielectrics and Its Application, Harbin 150080, China;College of Electronic & Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China ;Ministry of Education Key Laboratory of Engineer Dielectrics and Its Application, Harbin 150080, China;Dept.of Applied Chemistry, Harbin Institute Technology, Harbin 150001,China
Abstract:This article compares the traditional method with the microwave-assisted method of nano-MgO preparation, and analyses the influence of Mg(OH)2 synthesized by the two methods on nano-MgO grain size and surface morphology, as well as the influence of different nano-MgO preparation methods on space charge, volume resistivity and DC breakdown field strength of the MgO/LDPE nanocomposites. The results show that the grain size of nano-MgO prepared by the traditional method is 22.74 nm, while that prepared by the microwave-assisted method is 12.76 nm. When the MgO content is 2wt%, it can effectively reduce the space charge accumulation in the composite materials, and improve the volume resistivity and DC breakdown field strength.
Keywords:nano-MgO  microwave-assisted method  preparation  nanocomposites  dielectric properties
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