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重水中氢氧同位素的质谱分析
引用本文:李立武,杜晓宁.重水中氢氧同位素的质谱分析[J].同位素,2005,18(3):134-136.
作者姓名:李立武  杜晓宁
作者单位:1. 中国科学院,气体地球化学重点实验室,甘肃,兰州,730000
2. 上海化工研究院,上海,200062
摘    要:用高分辨率质谱计分析了重水中氢与氧的同位素组成;分析了重水的分子组成、质谱中的单电荷离子;利用高分辨率质谱峰相对强度,计算了重水中的氢氧同位素组成。结果表明,高分辨率质谱法分析重水,可同时分析其中的氢同位素和氧同位素,并且用样量小,结果可靠。

关 键 词:重水  氢同位素  氧同位素  质谱
文章编号:1000-7512(2005)03-0134-03
收稿时间:2004-09-09
修稿时间:2005-04-26

Isotope Mass Spectrum Analysis of Hydrogen and Oxygen in Heavy Water
LI Li-wu,DU Xiao-ning.Isotope Mass Spectrum Analysis of Hydrogen and Oxygen in Heavy Water[J].Isotopes,2005,18(3):134-136.
Authors:LI Li-wu  DU Xiao-ning
Affiliation:1. Key Laboratory of Gas Geochemistry, Chinese Academy of Sciences, Lanzhou 730000, China; 2. Shanghai Research Institute of Chemical Industry, Shanghai 200062, China
Abstract:The isotopic composition of hydrogen and oxygen in heavy water are analyzed by using a high-resolution mass spectrometer. The molecular forms and single-charged ions in the mass spectrum of heavy water are clarified. And the hydrogen and oxygen isotopic compositions in some heavy waters are calculated by the high-resolution mass spectrometer. The results show that hydrogen and oxygen isotopic composition can be analyzed in the same time by using high-resolution mass spectrometer, little sample is used and the results is reliable.
Keywords:heavy water  hydrogen isotope  oxygen isotope  mass spectrum
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