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Hydrazine-reduction of graphite- and graphene oxide
Authors:Sungjin Park  Jinho An  Jeffrey R Potts  Aruna Velamakanni  Shanthi Murali  Rodney S Ruoff
Affiliation:aDepartment of Mechanical Engineering and the Texas Materials Institute, The University of Texas at Austin, One University Station C2200, Austin, TX 78712-0292, USA;bDepartment of Chemistry, Inha University, Incheon 402-751, Republic of Korea
Abstract:We prepared hydrazine-reduced materials from both graphite oxide (GO) particles, which were not exfoliated, and completely exfoliated individual graphene oxide platelets, and then analyzed their chemical and structural properties by elemental analysis, XPS, TGA, XRD, and SEM. Both reduced materials showed distinctly different chemical and structural properties from one another. While hydrazine reduction of graphene oxide platelets produced agglomerates of exfoliated platelets, the reduction of GO particles produced particles that were not exfoliated. The degree of chemical reduction of reduced GO particles was lower than that of reduced graphene oxide and the BET surface area of reduced GO was much lower than that of reduced graphene oxide.
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