Synthesis and optical properties of vanadium dioxide nanoparticles in nanoporous glasses |
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Authors: | A I Sidorov O P Vinogradova I E Obyknovennaya T A Khrushchova |
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Affiliation: | (1) Vavilov Optical Institute, State Scientific Center of the Russian Federation, St. Petersburg, 190164, Russia |
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Abstract: | A method for the synthesis of vanadium dioxide (VO2) nanoparticles in nanoporous silicate glass matrices with a pore size of 17 and 7 nm has been developed. According to this, vanadium pentoxide (V2O5) nanoparticles are initially grown in the pores, and then V2O5 is reduced to VO2 in hydrogen. The optical transmission spectra of 1-mm-thick VO2-modified glass samples have been measured. The temperature dependence of the transmission coefficient has been studied in the course of the semiconductor-metal phase transition in VO2 nanoparticles. |
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