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木质活性炭自燃性质及其影响因素研究
引用本文:孙康,蒋剑春,戴伟娣,张燕萍.木质活性炭自燃性质及其影响因素研究[J].生物质化学工程,2010,44(1):9-13.
作者姓名:孙康  蒋剑春  戴伟娣  张燕萍
作者单位:1. 中国林业科学研究院, 林产化学工业研究所;生物质化学利用国家工程实验室; 国家林业局, 林产化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏 南京 210042;2. 中国林业科学研究院, 林业新技术研究所, 北京 100091
基金项目:“十一五”国家科技支撑计划资助((2006BAD19B06));;中央级公益性科研院所基本科研业务费专项资金(CAFINT2007C16)
摘    要:对6种木质活性炭自燃性质的影响因素进行了研究。研究表明活性炭的临界自燃温度与其制造工艺和设备有关。挥发分(碳氢氧化合物)、氧含量、氢含量和表面含氧官能团及粒度是影响活性炭临界自燃温度的主要因素。磷酸法活性炭临界自燃温度最低(180℃),水蒸气法活性炭由于经过1000℃活化过程,在试验范围内无自燃性质。另外,平板炉制造的粉状活性炭比回转炉制造的粉状活性炭的临界自燃温度高。

关 键 词:活性炭  自燃  元素组成  挥发分  表面官能团  
收稿时间:2009-09-27

Study on Self-ignition Character and Influence Factors of Woody Activated Carbon
SUN Kang,JIANG Jian-chun,DAI Wei-di,ZHANG Yan-ping.Study on Self-ignition Character and Influence Factors of Woody Activated Carbon[J].Biomass Chemical Engineering,2010,44(1):9-13.
Authors:SUN Kang  JIANG Jian-chun  DAI Wei-di  ZHANG Yan-ping
Affiliation:1. Institute of Chemical Industry of Forest Products, CAF;National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. on Forest Chemical Engineering, SFA;Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;2. Institute of New Technology of Forestry, CAF, Beijing 100091, China
Abstract:The influence factors on the self-ignition properties of six kinds of woody powdered activated carbon were studied. The critical self-ignition temperature (CIT) of activated carbon is related to manufacture processes and equipments. Studies have shown that volatile, oxygen, hydrogen and surface oxygen-containing functional groups are main factors that affect the CIT of activated carbon. Activated carbon manufactured by phosphoric acid has the lowest CIT (180℃), but the activated carbon manufactured by steam has the highest CIT since its activation temperature is high as 1000℃ and it has no self-ignition property. In addition, powdered activated carbon manufactured by flat furnace has higher CIT than that manufactured by rotary furnace.
Keywords:activated carbon  self-ignition  element composition  volatilite  surface functional group  
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