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Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase |
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| Authors: | Taisuke Tokunaga Takeshi Yatabe Takahiro Matsumoto Tatsuya Ando Ki-Seok Yoon |
| Affiliation: | 1. International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka, Japan;2. Center for Small Molecule Energy, Kyushu University, Fukuoka, Japan;3. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, Japan |
| Abstract: | AbstractWe report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction. |
| Keywords: | Mechanistic investigation H2 evolution formic acid formate hydrogen lyase model dinuclear Ru complex |