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外环流氨化反应器数学模型及放大设计
引用本文:刘期崇,付红梅,夏代宽,张允湘,王建华,程建方,何鹏程,白元林,曹尚崇.外环流氨化反应器数学模型及放大设计[J].磷肥与复肥,2000,15(1):12-17.
作者姓名:刘期崇  付红梅  夏代宽  张允湘  王建华  程建方  何鹏程  白元林  曹尚崇
作者单位:1. 四川大学化工学院,四川,成都,610065
2. 铜化集团公司磷铵厂,安徽,铜陵,244023
3. 绵竹磷肥厂,四川,绵竹,618201
摘    要:研究了外环流氨化反应器的流动模型、传质模型和放大设计。结果表明,在工业条件下.此反应器的流动模型接近于全混流,传质模型为=(pH)-2.1。应用此模型已将反应器放大到年产6万吨磷酸一铵和16万吨磷酸二铵,装置运行稳定,产品合格。

关 键 词:外环流反应器  数学模型  放大设计  磷铵
文章编号:1007-6220(2D00)01-0012-06
修稿时间:1999-06-07

The mathematical model and scaling - up design of ammoniator with external circulation
LIU Qi-chong,FU Hong-mei,XIA Dai-kuan,ZHANG Yun-xiang,WANG Jian-hun,CHENG Jian-fang,HE Peng-cheng,BAI Yuan-lin,CAO Shang-chong.The mathematical model and scaling - up design of ammoniator with external circulation[J].Phosphate & Compound Fertilizer,2000,15(1):12-17.
Authors:LIU Qi-chong  FU Hong-mei  XIA Dai-kuan  ZHANG Yun-xiang  WANG Jian-hun  CHENG Jian-fang  HE Peng-cheng  BAI Yuan-lin  CAO Shang-chong
Affiliation:LIU Qi-chong ,FU Hong-mei ,XIA Dai-kuan ,ZHANG Yun-xiang ,WANG Jian-hun ;(Institute of Chemical Engineering, Sichaan University, Chengdu, Sichuan 610065, China);CHENG Jian-fang ;(Tongllng Ammanium Phosphate Plant, Tongling, Anhui 244023, China)
Abstract:The mathematical model and scalingup design were studied for ammoniator with external circulation . Result shows that the flow model of the reactor approaches to perfect mixed flow at industrial conditions. The model of mass transfer is k \-\{ G \}a=20 G a \ \{0.3\} q a \ \{1.2\}(pH)\ \{-2.1\}. Based on the model, the ammoniator has been scaled up to an industrial reactor with the capacity of 60 kt/a MAP and 160 kt/a DAP, and are well operated.
Keywords:reactor with external circulation    mathematical model    scaling-up design    ammonium phosphate
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