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影响氯磺化聚乙烯/丁腈橡胶共混物耐热老化性能的因素
引用本文:陈焜盛,罗权焜.影响氯磺化聚乙烯/丁腈橡胶共混物耐热老化性能的因素[J].合成橡胶工业,2006,29(5):360-363.
作者姓名:陈焜盛  罗权焜
作者单位:华南理工大学,材料科学与工程学院,广东,广州,510640
摘    要:研究了氯磺化聚乙烯(CSM)和丁腈橡胶(NBR)的共混比、硫黄用量、炭黑、防老剂及软化剂诸因素对CSM/NBR共混物耐热老化性能的影响。结果表明,将CSM与NBR共混,可以改善NBR的耐热老化性能,当CSM/NBR共混比(质量比)为50/50时,耐热老化性能得到显著提高。适当减少硫黄用量,有利于保持较高的耐热老化性能,硫黄用量以0.25~0.75份为宜。炭黑用量对共混物的耐热老化性能有影响,随着炭黑N 550用量的增加,老化后的力学性能保持率先增加后减小。防老剂NBC的耐热老化效果较好。软化剂选用邻苯二甲酸二丁酯或邻苯二甲酸二辛酯时,CSM/NBR共混物具有较好的耐热老化性能。

关 键 词:氯磺化聚乙烯  丁腈橡胶  共混物  耐热老化性能
文章编号:1000-1255(2006)05-0360-04
收稿时间:2005-06-22
修稿时间:2005-06-222006-04-29

Effective factors of heat aging resistance of chlorosulfonyl-polyethylene/acrylonitrile-butadiene rubber blends
Chen Kunsheng,Luo Quankun.Effective factors of heat aging resistance of chlorosulfonyl-polyethylene/acrylonitrile-butadiene rubber blends[J].China Synthetic Rubber Industry,2006,29(5):360-363.
Authors:Chen Kunsheng  Luo Quankun
Affiliation:College of Materials Science and Engineering, South China University Technology, Guangzhou 510640, China
Abstract:The effect of ratio of chlorosulfonyl-polyethylene(CSM) and acrylonitrile-butadiene rubber(NBR),sulfur,carbon black,antioxidant and softening agent on the heat aging resistance of CSM/NBR blends were investigated.The results showed that the heat aging resistance of NBR increased when CSM blends with it and the mass ratio of CSM/NBR was(50/50.) When the amount of sulfur was decreased,the heat aging resistance of the blends were better,the optimum(amount) was 0.25~ 0.75 phr.The heat aging resistance increased first then decreased with the increase of amount of carbon black N 550.The heat aging resistance of CSM/NBR were better when the antioxidant NBC,the softening agent dibutyl phthalate or diocthl phthalate was used.
Keywords:chlorosulfonyl-polyethylene  acrylonitrile-butadiene rubber  blend  heat aging resistance
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