| 高氯酸羟胺热分解动力学 |
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| 引用本文： | 米镇涛,常志华,张香文,邱立勤,王亚权.高氯酸羟胺热分解动力学[J].化工学报,2000,51(1):133-136. |
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| 作者姓名： | 米镇涛 常志华 张香文 邱立勤 王亚权 |
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| 作者单位： | 天津大学化工学院!天津300072,天津大学化工学院!天津300072,天津大学化工学院!天津300072,天津大学化工学院!天津300072,天津大学化工学院!天津300072 |
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| 摘 要： | 引言 高氯酸羟胺(HAP)是一种用于推进技术领域的新型高能氧化剂,在高性能推进系统中具有极为重要的价值1～3].
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| 关 键 词： | 高氯酸羟胺 分解动力学 热分析 氧化剂 推进剂 |
KINETICS OF THERMAL DECOMPOSITION OF HYDROXYLAMINE PERCHLORATE |
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| Mi Zhentao,Chang Zhihua,Zhang Xiangwen,Qiu Liqin,Wang Yaquan.KINETICS OF THERMAL DECOMPOSITION OF HYDROXYLAMINE PERCHLORATE[J].Journal of Chemical Industry and Engineering(China),2000,51(1):133-136. |
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| Authors: | Mi Zhentao Chang Zhihua Zhang Xiangwen Qiu Liqin Wang Yaquan |
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| Abstract: | Hydroxylamine perchlorate (HAP) is a new energetic oxidizer. The thermal decomposition of pure HAP and the effects of additives on thermal decomposition of HAP were studied by using TG and DTA in nitrogen atmosphere. The additives are 4 0% NH 4ClO 4, 3 0% HClO 4, and 0 29% FeCl 3 respectively. The TG curves of the above four systems were determined. The experimental results indcate that FeCl 3 has a promoting effect on the decomposition of HAP,but NH 4ClO 4 and HClO 4 have no such effect on the decomposition of HAP. NH 4ClO 4 acts as an inert substance, and HClO 4 has a weak retarding effect on the decomposition of HAP. By using non isothermal TG DTG,the thermal decomposition kinetic equations of the four systems were obtained. Through comparing the kinetic parameters of the four systems,the order of decomposition activation energy ( E ) and reaction order ( n ) were found: HAP+0 29% FeCl 3
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| Keywords: | hydroxylamine perchlorate decomposition kinetics thermal analysis |
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