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Effects of virgin Ethylene–Propylene–Diene–Monomer and its preheating time on the properties of natural rubber/recycled Ethylene–Propylene–Diene–Monomer blends
Affiliation:1. Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, United States;2. Department of Chemistry, University of Utah, Salt Lake City, UT 84112, United States;1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350108, China;2. College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China;3. University of Chinese Academy of Sciences, Beijing 100049, China;1. Institute of Carbon Technology, Jeonju University, 303 Cheonjam-ro, Wansan-gu, Jeonju-si, Jeollabuk-do 55069, Republic of Korea;2. Department of Organic Materials & Fiber Engineering, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju-si, Jeollabuk-do 561-756, Republic of Korea;3. Department of Mechanical & Automotive Engineering, Jeonju University, 303 Cheonjam-ro, Wansan-gu, Jeonju-si, Jeollabuk-do 55069, Republic of Korea;4. Department of Manufacturing Technology and Design Engineering, Jeonju University, 303 Cheonjam-ro, Wansan-gu, Jeonju-si, Jeollabuk-do 55069, Republic of Korea;1. Department of Materials Science and Engineering, National Taiwan University of Science and Technology, 43, Section 4, Keelung Road, Taipei 106, Taiwan, ROC;2. Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan, ROC;3. Department of Chemical Engineering, Feng Chia University, 100, Wenhwa Road, Seatwen, Taichung 40724, Taiwan, ROC;1. Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland;2. The Joint Institute for Power and Nuclear Research, Minsk-Sosny, Belarus
Abstract:Blending of natural rubber/recycled Ethylene–Propylene–Diene–Monomer (NR/R-EPDM) blends was carried out. A fixed amount of carbon black and virgin Ethylene–Propylene–Diene–Monomer (EPDM) were also introduced into the blends. Applications of two different processing methods were carried out to improve the cure compatibility, crosslink distribution, and hence mechanical properties of the blends. Simple processing method was done by mixing the entire additives and rubbers on a laboratory-sized two-roll-mill at ambient temperature. Whereas, reactive processing method was conducted by mixing virgin EPDM, recycled EPDM and other compounding ingredients using an internal mixer, the compound was later preheated according to designated time before blending with natural rubber and carbon black. Results revealed that the enhancement of the physical and mechanical properties was significantly achieved towards preheating time of EPDM/R-EPDM blends. The improved properties in the blends suggested that the reactive processing method had led to more homogeneous blends due to a better crosslink distribution and more homogeneous carbon black distribution.
Keywords:Natural rubber  Recycled Ethylene–Propylene–Diene–Monomer  Preheating time  Mechanical properties  Reactive processing
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