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Printability of functional inks on multilayer curtain coated paper
Affiliation:1. Center for Functional Materials, Turku, Finland;2. Paper Coating and Converting, Department of Chemical Engineering, Åbo Akademi University, Turku, Finland;3. Physics, Department of Natural Sciences, Åbo Akademi University, Turku, Finland;4. Graduate School of Materials Research, Turku, Finland;5. Styron Europe GmbH, CH 8833 Samstagern, Switzerland;6. Imerys Minerals Ltd., Par Moor Centre, Cornwall, England, United Kingdom;1. Department of Applied Chemistry, S. V. National Institute of Technology, Surat, 395007, Gujarat, India;2. Analytical Chemistry Division, Bhabha Atomic Research Center, Trombay, Mumbai, 400085, India;1. Department of Mathematics, IIT Kharagpur 721302, India;2. Department of Mechanical Engineering, IIT Kharagpur 721302, India;1. Department of Mechanical Design and Production Engineering, Konkuk University, Seoul, 05029, Republic of Korea;2. Department of Organic and Nano System Engineering, Konkuk University, Seoul, 05029, Republic of Korea;3. Department of Polymer Science and Engineering, University of Massachusetts Amherst, 120 Governors Drive, Amherst, MA, 01003, United States;1. Sapienza University of Rome, Department of Astronautical, Electrical and Energy Engineering (DIAEE), Via Eudossiana 18, 00184 Rome, Italy;2. Research Center for Nanotechnology applied to Engineering of Sapienza University (CNIS), Piazzale Aldo Moro 5, 00185 Rome, Italy;3. CNR – ISMN, P.O. Box 10, 00015 Monterotondo Stazione, Rome, Italy;1. State Key Laboratory of Automotive Safety and Energy, School of Vehicle and Mobility, Tsinghua University, Beijing 100084, China;2. Center for Combustion Energy, Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China;3. Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE, UK
Abstract:Printability of functional inks on multilayer curtain coated substrates was investigated. The inks represent those commonly used to produce solution processable electronic devices, such as organic transistors. The substrate, which combines sufficient barrier and printability properties for printed functional devices, was manufactured utilizing high speed curtain coating technique. The coating structure consists of a mineral pigment layer coated on top of a barrier layer. The combination of the two layers allows for controlling the absorption of ink solvents. By adjusting the thickness, porosity and surface energy of the top-coating the printability can be tuned for various functional inks. Focus was set on printing conducting silver and carbon inks, both with nano- and micrometer sized particles, as well as printing of an organic semiconductor, poly(3-hexylthiophene). The pore volume in the top-coating determined the spreading of the micrometer sized silver ink as well as the amount semiconductor per area required, whereas the pore size was the determining factor regarding penetration of the nano-sized silver ink. As a proof of concept hygroscopic insulator field effect transistors were printed on the multi-layer curtain coated paper using a custom-built roll to roll hybrid printer.
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