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Vapor Pressures of Zinc Over AgZn Alloys
Authors:E E Underwood  B L Averbach
Affiliation:1.Dept. of Metallurgy,USA;2.Massachusetts Institute of Technology,Cambridge,USA
Abstract:The vapor pressure of zinc in equilibrium with solid β AgZn alloys has been measured by the dew-point method. The thermodynamic activities of silver, and the molar heats of formation have been calculated. Similar measurements have been made for the ternary alloys formed by adding gold to AgZn. An apparent particle size effect has been observed for AgZn filings. The vapor pressure of zinc over filings is 15 to 20 pct higher than over the solid alloys.
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