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气态膜在烧结脱硫脱硝制酸废水处理中的应用
引用本文:杨本涛,赵利明,彭杰,刘义,魏进超.气态膜在烧结脱硫脱硝制酸废水处理中的应用[J].水处理技术,2021(4):125-127,132.
作者姓名:杨本涛  赵利明  彭杰  刘义  魏进超
作者单位:中冶长天国际工程有限责任公司;国家烧结球团装备系统工程技术研究中心;宝钢湛江钢铁有限公司炼铁厂
基金项目:湖南省重点研发计划(2018SK2026);湖南省自然科学基金(2018JJ3894)。
摘    要:以某钢铁厂烧结工序脱硫脱硝制酸产生的高NH4+-N含量废水为处理对象,采用疏水性的聚丙烯(PP)中空纤维气态膜进行了废水中NH4+-N的脱除和回收工业化应用实验。结果表明,通过良好设计和过程控制,出水NH4+-N的质量浓度均低于15 mg/L,最低为1.2 mg/L,满足GB 13456-2012排放限值要求,且运行稳定。副产的硫酸铵品质稳定,质量分数在10%~18%。

关 键 词:气态膜  硫脱硝制酸废水  氨氮  工业化应用

Application on Gaseous Membrane in the Treatment of Sintering Desulfurization,Denitrification and Acid Production Wastewater
YANG Bentao,ZHAO Liming,PENG Jie,LIU Yi,WEI Jinchao.Application on Gaseous Membrane in the Treatment of Sintering Desulfurization,Denitrification and Acid Production Wastewater[J].Technology of Water Treatment,2021(4):125-127,132.
Authors:YANG Bentao  ZHAO Liming  PENG Jie  LIU Yi  WEI Jinchao
Affiliation:(Zhongye Changtian International Engineering Co.,Ltd,Changsha 410205,China;National Sintering and Pelletizing Equipment System Engineering Research Center,Changsha 410205,China;Ironmaking Plant,Baosteel Zhanjiang Iron and Steel Co.,Ltd,Zhanjiang 524072,China)
Abstract:Hydrophobic polypropylene(PP) hollow fiber gaseous membrane was used to carry out the industrialized application experiment on the removal and recovery of NH4+-N in wastewater,regarding the high concentration NH4+-N wastewater generated by the flue gas desulfurization and denitrification system in sintering process of a certain steel plant as the research object.The results showed that,though good design and process control,the mass concentration of NH4+-N in effluent was below 15 mg/L,te lowest value reached 1.2 mg/L,which met the emission limit requirements of GB13456-2012 and the operation was stable.The quality of by-product ammonium sulfate was stable,with a mass fraction of 10% to 18%.
Keywords:gaseous membrane  desulfurization  denitrification and acid production wastewater  ammonia nitrogen  industrialized application
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