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PE-LLD/SEBS-g-MAH/POE-g-MAH共混体系流变性能的研究
引用本文:罗永春;仲豪;熊煦;龚方红.PE-LLD/SEBS-g-MAH/POE-g-MAH共混体系流变性能的研究[J].中国塑料,2010,24(5):63-67.
作者姓名:罗永春;仲豪;熊煦;龚方红
作者单位:江苏工业学院 江苏工业学院
摘    要:在双螺杆挤出机中用马来酸酐(MAH)分别对乙烯-辛烯共聚物(POE)、氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)进行熔融接枝,用密炼机对线形低密度聚乙烯(PE-LLD)、POE-g-MAH和SEBS-g-MAH进行熔融共混,用毛细管流变仪对PE-LLD/SEBS-g-MAH二元体系和PE-LLD/POE-g-MAH/SEBS-g-MAH三元体系的流变行为进行研究。结果表明,LLDPE/POE-g-MAH/SEBS-g-MAH共混体系是典型的假塑性流体;体系的表观黏度随着SEBS-g-MAH组分含量的增加而增加,POE-g-MAH对共混体系表观黏度的影响较小。

关 键 词:线形低密度聚乙烯  马来酸酐接枝乙烯-辛烯共聚物  马来酸酐接枝氢化苯乙烯-丁二烯-苯乙烯嵌段共聚物  共混体系  流变性能  
收稿时间:2010-1-22

Rheological Behavior of PE-LLD/SEBS-g-MAH/POE-g-MAH Blends
LUO Yongchun Hao ZHONG Xu XIONG Fanghong GONG.Rheological Behavior of PE-LLD/SEBS-g-MAH/POE-g-MAH Blends[J].China Plastics,2010,24(5):63-67.
Authors:LUO Yongchun Hao ZHONG Xu XIONG Fanghong GONG
Abstract:POE and SEBS was melt grafted with MAH in a twin-screw extruder separately, and introduced into PE-LLD forming binary blends PE-LLD/SEBS-g-MAH and ternary blends PE-LLD/POE-g-MAH/SEBS-g-MAH in a internal mixer. The rheological property of the blends was studied using a capillary rheometer. The ternary blend was found a typical pseudo-plastic melt. The apparent viscosity increased with increasing content of SEBS-g-MAH, and the influence of POE-g-MAH on the apparent viscosity of the blends was negligible.
Keywords:linear low-density polyethylene  ethylene-octene copolymer grafted maleic anhydride  hydrogenated styrene-butadiene-styrene copolymer grafted maleic anhydride  blending system  rheological behavior  
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