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高含量氧化铝对EVA胶膜导热性能的影响
引用本文:申明霞,崔寅鑫,何辉,李红香,陈庆民. 高含量氧化铝对EVA胶膜导热性能的影响[J]. 高分子材料科学与工程, 2009, 0(10)
作者姓名:申明霞  崔寅鑫  何辉  李红香  陈庆民
作者单位:河海大学材料科学与工程学院;南京大学化学化工学院高分子科学与工程系;
基金项目:国家863资助项目(2006AA050203-2)
摘    要:制备了高填充Al2O3/EVA复合胶膜。研究了Al2O3粒径、用量及表面性质等对复合胶膜导热性、力学性能以及粘合性的影响。采用激光闪射法测定了胶膜的导热性,动态粘弹谱仪测定了其动态粘弹性,热重分析仪测定了胶膜热失重曲线,并采用扫描电镜(SEM)观察了复合胶膜中Al2O3的分散和界面结合状态。结果表明,加入乙烯醋酸乙烯酯(EVA)胶膜质量80%的偶联剂改性Al2O3,可使复合胶膜导热系数提高1.2倍以上,Al2O3/EVA界面结合良好;热稳定性提高,而且胶膜具有良好粘合性和较高强韧性。

关 键 词:光伏(PV)组件  乙烯醋酸乙烯酯胶膜  导热系数  氧化铝  粘合性  

The Influence of High-Al_2O_3 on the Thermal Conductivity of EVA Film
SHEN Ming-xia,CUI Yin-xin,HE Hui,LI Hong-xiang,CHEN Qing-min. The Influence of High-Al_2O_3 on the Thermal Conductivity of EVA Film[J]. Polymer Materials Science & Engineering, 2009, 0(10)
Authors:SHEN Ming-xia  CUI Yin-xin  HE Hui  LI Hong-xiang  CHEN Qing-min
Affiliation:SHEN Ming-xia1,2,CUI Yin-xin1,HE Hui1,LI Hong-xiang1,CHEN Qing-min2(1.College of Material Science & Engineering,Hohai University,Nanjing 210098,China,2.Department of Polymeric Science & Engineering,Nanjing University,Nanjing 210093,China)
Abstract:Aluminium oxide/ethylene-vinyl acetate copolymer(Al2O3/EVA) co-film with high content of Al2O3 was prepared.The effects of particle scale and amount and surface property of Al2O3 on thermal conductivity and tensile properties and adhesion of the co-film were discussed.The laser flash analyzer and dynamic mechanical analysis were used to measure the thermal conductivity and viscoelasticity of the film.And the interface of Al2O3/EVA was observed by scan electronic microscope(SEM).The conclusion shows that,the...
Keywords:photovoltaic(PV)module  EVA film  thermal conductivity  Al2O3  adhesion  
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