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Thermally Stable Transparent Resistive Random Access Memory based on All‐Oxide Heterostructures
Authors:Jie Shang  Gang Liu  Huali Yang  Xiaojian Zhu  Xinxin Chen  Hongwei Tan  Benlin Hu  Liang Pan  Wuhong Xue  Run‐Wei Li
Affiliation:1. CAS Key Laboratory of Magnetic, Materials and Devices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, P. R. China;2. Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, P. R. China
Abstract:An all‐oxide transparent resistive random access memory (T‐RRAM) device based on hafnium oxide (HfOx) storage layer and indium‐tin oxide (ITO) electrodes is fabricated in this work. The memory device demonstrates not only good optical transmittance but also a forming‐free bipolar resistive switching behavior with room‐temperature ROFF/RON ratio of 45, excellent endurance of ≈5 × 107 cycles and long retention time over 106 s. More importantly, the HfOx based RRAM carries great ability of anti‐thermal shock over a wide temperature range of 10 K to 490 K, and the high ROFF/RON ratio of ≈40 can be well maintained under extreme working conditions. The field‐induced electrochemical formation and rupture of the robust metal‐rich conductive filaments in the mixed‐structure hafnium oxide film are found to be responsible for the excellent resistance switching of the T‐RRAM devices. The present all‐oxide devices are of great potential for future thermally stable transparent electronic applications.
Keywords:transparent electronics  random access memory  hafnium oxide  all‐oxide  thermally stable
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