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二烷基二硫代氨基甲酸钼在锂基润滑脂中的摩擦学性能
引用本文:夏迪,陈国需,程鹏,任改梅.二烷基二硫代氨基甲酸钼在锂基润滑脂中的摩擦学性能[J].石油炼制与化工,2015,46(5):88-92.
作者姓名:夏迪  陈国需  程鹏  任改梅
作者单位:1. 后勤工程学院军事油料应用与管理工程系; 2. 后勤工程学院化学与材料工程系; 3. 湖南省华京材料粉体有限公司
基金项目:中国人民解放军全军后勤计划项目
摘    要:合成了有机钼化合物二烷基二硫代氨基甲酸钼(MoDTC),并确定主要官能团及元素含量。采用热重分析仪测试了其热稳定性能;采用四球摩擦磨损机评价了其在锂基润滑脂中的摩擦学性能,并与二硫化钼(MoS2)进行对比。结果表明:MoDTC具有优良的热稳定性能;载荷为392N时,MoDTC添加量为3.0%时达到最佳减摩作用,比基础脂试验时平均摩擦因数降低40.2%,添加量为2.0%时到达最佳抗磨作用,比基础脂试验后钢球磨斑直径减小29.8%。

收稿时间:2014-11-06

TRIBOLOGICAL PROPERTIES OF MOLYBDENUM DIALKYLDITHIOCARBAMATE IN LITHIUM BASE GREASE
Abstract:he organic molybdenum compound, molybdenum dialkydithiocarbamate (MoDTC), was prepared. The functional group and element content of the compound was determined. The thermal stability was tested by TG-DSC. Its tribological properties in lithium base grease were evaluated by four-ball friction tester and compared with MoS2. The results show that MoDTC possesses a good thermal stability, the physicochemical property of the lithium base adding MoDTC grease is unchanged. Compared with the blank lithium base grease, at 392 N loading, the best anti-friction effect is achieved at 3.0% of MoDTC in grease, the average friction coefficient could reduce by 40.2%, and the mass fraction of MoDTC in grease is 2.0%, when the wear scar diameter is reduced by 29.8%.
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