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磷钼酚醛树脂的热分析研究
引用本文:赵会明,郑怀礼.磷钼酚醛树脂的热分析研究[J].工程塑料应用,2001,29(5):28-29.
作者姓名:赵会明  郑怀礼
作者单位:重庆大学应用科学与技术系
摘    要:以六次甲基四胺为磷钼酚醛树脂的固化剂,采用热重分析法研究了固化剂用量对磷钼酚醛树脂性能的影响和磷钼酚醛树脂的固化反应表观动力学。结果表明,磷钼酚醛树脂与固化剂配比为100:10时,700℃下失重率为30.3%,热分解温度为791.7℃,磷钼酚醛树脂固化反应的表观活化能为21.11kJ/mol。

关 键 词:磷钼酚醛树酯  热重分析  固化剂  耐烧蚀  高分子材料
修稿时间:2001年1月28日

STUDY ON THE THERMAL ANALYSIS OF THE P-Mo PHENOLIC-FORMALDEHYDE RESIN
Zhao Huiming,Zheng Huaili.STUDY ON THE THERMAL ANALYSIS OF THE P-Mo PHENOLIC-FORMALDEHYDE RESIN[J].Engineering Plastics Application,2001,29(5):28-29.
Authors:Zhao Huiming  Zheng Huaili
Abstract:The influence of amount of the curing agent on P-Mo Phenolic-formaldehyde resin is studied by thermal-weight analysis.The immobilizafion agent of P-Mo Phenolic-formaldehyde resin is hexamethylenetetramine. The apparent kinetic for action of immobilization agent is also studied. The ratio of P-Mo phenolic-formaldehyde resin to immobilization agent is 100: 10, the lost ratio of weight is 30.3% at700℃.The temperature of thermal decomposability is 791.7℃. The apparent active energy is 21.11 kJ/mol.
Keywords:P-Mo phenolic-fonnaldehyde resin  thermal-weight analysis  curing agent  polymer material
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