琼东南盆地煤地球化学特征

琼东南盆地煤层主要分布于下渐新统崖城组,煤样的灰分含量在13.59%~58.33%之间,炭质泥岩灰分含量在56.08%~81.33%之间,煤中灰分来源于煤中的矿物质。煤样中的矿物质主要为粘土、硫化物(黄铁矿)和石英等。煤样全硫含量在1.07%~6.39%之间,大多数煤为高硫煤。煤样均为烟煤,煤样挥发份含量在17.97%~33.53%之间。煤的有机组分总量在61.7%~96.1%之间,炭质泥岩样品有机组分总量在38.5%~59.8%之间。样品的显微有机组分以镜质组为主,其含量在58.4%~98%之间;惰质组次之,含量在1.4%~3.5%之间;煤样几乎不含壳质组。煤样中微镜煤含量在46.7%~93.2%之间,炭质泥岩样品中微镜煤含量在18.2%~31.6%之间。由于煤中矿物组分、挥发份及硫分含量相对较高,该地区煤的碳含量较低,最低为25.09%,最高为65.60%,其碳含量明显低于烟煤碳含量。焦渣以粘着、弱粘性和不熔融粘结为主。煤样最大镜质组反射率在1.04%~1.23%之间,平均值为1.14%,反映了煤岩的变质程度较高,在肥煤—焦煤之间,为中等变质程度的烟煤,正处于煤化作用的第二次跃变阶段,有利于气体的大量排出,在合适的保存条件下,有利于形成煤成气田。

Coal Geochemistry of Qiongdongnan Basin

The coal bed of Qiongdongnan basin distributes mainly in Yacheng Formation of lower Oligocene.Ash contents of coal samples are 13.59%-58.33%,and of carbonaceous mudstone samples are 56.08%-81.33%.Minerals of the coal samples consist of clay,sulfides(pyrite) and quartz.Total sulfur contents of coal samples are 1.07%-6.39% and most of the samples are high-sulfur coal.All the coal samples are bituminous coal with 17.97%-33.53% volatile matter.Total organic contents are 61.7%-96.1% of the coal samples and 38.5%...