Effects of PVA content on the synthesis of LaFeO3 via sol-gel route

LaFeO₃ were synthesized via a sol-gel route based on polyvinyl alcohol (PVA). Differential scanning calorimetry (DSC), Thermogravimetric (TG), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Raman spectroscopy and field emission scanning electron microscopy (FESEM) techniques were used to characterize precursors and derived oxide powders. The effect of the ratios of positively charged valences to hydroxyl groups of PVA (Mⁿ⁺/-OH) on the formation of LaFeO₃ was investigated. XRD analysis showed that single-phase and well-crystallized LaFeO₃ was obtained from the Mⁿ⁺/-OH = 4:1 molar ratio precursor at 700 °C. For the precursor with Mⁿ⁺/-OH = 2:1, nanocrystalline LaFeO₃ with average particle size of ∼50 nm was formed directly in the charring procedure. With increase of PVA content to Mⁿ⁺/-OH = 1:1, phase pure LaFeO₃ was obtained at 500 °C.