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Synthesis and characterization of clinopyroxene based glasses and glass-ceramics along diopside (CaMgSi2O6)-jadeite (NaAlSi2O6) join
Authors:Rinkel Jindal  R. JayaganthanIndra Vir Singh  Reinhard Conradt
Affiliation:a Department of Metallurgical and Materials Engineering & Centre of Nano-technology, Indian Institute of Technology Roorkee, Roorkee 247667, India
b Department of Glass and Ceramic Composites, Institute of Mineral Engineering, RWTH Aachen, Mauerstr. 5, 52064 Aachen, Germany
c Department of Mechanical and Industrial Engineering, Indian Institute of Technology Roorkee, Roorkee 247667, India
Abstract:The crystallization behavior and mechanical characterization of glasses based upon the compositions along diopside (CaMgSi2O6)-jadeite (NaAlSi2O6) join has been investigated. Six glasses were obtained by the melt-quenching technique. Structural and thermal behaviors of these glasses were investigated by density and molar volume, infrared spectroscopy (FTIR) and dilatometry. The crystallization behavior of glasses was investigated by using differential scanning calorimetry (DSC). Sintering and crystallization behavior of the glass-ceramics were investigated under non-isothermal heating conditions up to temperatures of 850 °C. Mechanical characterization of glasses was investigated by using the measurement of Vickers indentation hardness and elastic constants such as Young's modulus (E), shear modulus (G), bulk modulus (K) and Poisson's ratio (ν). These data of the glasses were correlated with the structure of glasses, nature and role played by glass forming cations.
Keywords:C. Mechanical properties   C. Hardness   D. Glass
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